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学科主题: 天然产物有机化学
题名: An efficient and convenient approach to the total synthesis of sphingofungin
其他题名: 一种有效和方便的Sphingofungin F 的全合成途径
作者: Liu DG(刘定国) ; Wang L(王立) ; Lin GQ(林国强)
通讯作者: 林国强
刊名: J. Org. Chem.
发表日期: 2000-01-01
卷: 65, 期:26, 页:9114-9119
收录类别: SCI
部门归属: 中国科学院上海有机化学研究所
英文摘要: As a new member of the sphingofungin family, sphingofungin F exhibits interesting physiological activities with a structural unit of an α-substituted alanine. Described herein is an efficient and convenient stereoselective synthesis of sphingofungin F from L-(+)-tartaric acid, which utilizes sharpless asymmetric epoxidation of allylic alcohol and lewis acid-catalyzed intramolecular epoxideopening reaction with an n-nucleophile, to introduce the other two desired stereogenic centers. Side chain functionality was incorporated into the chiral segment using a Wittig reaction.
语种: 英语
相关网址: 查看原文
WOS记录号: WOS:000166089600036
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内容类型: 期刊论文
URI标识: http://ir.sioc.ac.cn/handle/331003/16565
Appears in Collections:中科院天然产物有机化学重点实验室_期刊论文

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Recommended Citation:
Liu DG,Wang L,Lin GQ. An efficient and convenient approach to the total synthesis of sphingofungin[J]. J. Org. Chem.,2000,65(26):9114-9119.
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