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学科主题: 天然产物有机化学
题名: Synthesis of optically pure clausenamine-A and its demethoxylated analogs
其他题名: 光学纯Clausenamine-A 及其衍生物的合成
作者: Lin GQ(林国强) ; Zhang AM(张爱民)
通讯作者: 林国强
刊名: Tetrahedron
发表日期: 2000
卷: 56, 期:37, 页:7163-7171
收录类别: SCI
部门归属: 中国科学院上海有机化学研究所
英文摘要: The first total synthesis of clausenamine-A (3) was developed involving the suzuki cross-coupling and oxidative coupling reaction. The synthesis of its demethoxylated analogs 1 and 2 were also reported. Resolution of (+)-1, (+)-2, (+)-3, and (-)-1, (-)-2, (-)-3 were performed via their corresponding camphorsulfonateds of the reacemates. The absolute configurations of (+)-1, (+)-2, (+)-3 and (-)-1, (-)-2, (-)-3 were assigned as (aR) and (aS), respectively, by X-ray analysis and their CD spectrum. The primarily cytotoxic activities of these biscarbazoles agains plasmodium falciparum were briefly described.
语种: 英语
相关网址: 查看原文
WOS记录号: WOS:000089149200008
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内容类型: 期刊论文
URI标识: http://ir.sioc.ac.cn/handle/331003/16545
Appears in Collections:中科院天然产物有机化学重点实验室_期刊论文

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Recommended Citation:
Lin GQ,Zhang AM. Synthesis of optically pure clausenamine-A and its demethoxylated analogs[J]. Tetrahedron,2000,56(37):7163-7171.
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