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学科主题: 有机氟化学
题名: The reaction of sodium perfluoroalkanesufinates with coumarin
其他题名: 全氟烷基亚磺酸盐与香豆素的反应
作者: Liu JT(刘金涛) ; Huang WY(黄维垣)
通讯作者: 刘金涛
刊名: J. Fluor. Chem.
发表日期: 1999
卷: 95, 页:131-133
收录类别: SCI
部门归属: 中国科学院上海有机化学研究所元素有机化学研究室
英文摘要: The reaction of sodium perfluoroalkanesufinates with coumarin in the presence of Mn(Oac)=3.2H=2O was studied. Sodium perfluoroalkanesufinates, R=FSO=2Na[R=FF(CF=2)=6, 2a; F(CF=2)=7, 2b; F(CF=2)=8, 2c; Cl(CE=2)=4, 2d; Cl(CF=2)=6, 2e] reacted readily with a small excess of coumarin to give the corresponding 3-perfluoroalkylated coumarins (3a-e), while poly-perfluoroalkylation of coumarin occurred when excess 2 was used in the reaction, and 3,6-diperfluoroalkylcoumarins (4) and 3,6,8-triperfluoroalkylcoumarins (5) were isolated as major products according to the ratio of starting materials.
语种: 英语
相关网址: 查看原文
WOS记录号: WOS:000080934900015
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内容类型: 期刊论文
URI标识: http://ir.sioc.ac.cn/handle/331003/16381
Appears in Collections:中科院有机氟化学重点实验室_期刊论文

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Recommended Citation:
Liu JT,Huang WY. The reaction of sodium perfluoroalkanesufinates with coumarin[J]. J. Fluor. Chem.,1999,95:131-133.
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