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Synthesis and characterization of a novel fluorine containing hydrophobically associating polymer
其他题名一类新型含氟疏水缔合型高分子的合成及表征
Yang J(杨进); Huang WY(黄维垣)
1999
发表期刊Chin. J. Polym. Sci.
ISSN0256-7679
卷号17期号:3页码:281-288
摘要In this article, the syntheisis and characterization of a novel fluoromonomer and its copolymer with acrylamide is reported. 2-perfluoroamyl-4-hydroxylquinoline 2 was synthesized from ethyl 2,2-dihydroperfluoroheptanoate in high yield. The monomer 4 was then synthesized from 2 in two steps readily in high yields. Synthesis and characterization of copolymers of acrylamide (AM) and the fluoromonomer were investigated. The composition and intrinsic viscosity of these copolymers were studied. It was found that the rhelological properties of aqueous solutions of polyacrylamide were modified significantly when a small proportion of the fluoromonomer 4 was incorporated on investigating the viscosity-concentration profiles, pseudoplasticity of these solutions and the effect of the presence of surfactant. These results could be explained by the hydrophobic association of the fluorocarbon segments in the aqueous solutions of these copolymers.
学科领域有机氟化学
部门归属中国科学院上海有机化学研究所元素有机化学研究室
收录类别SCI
语种英语
文献类型期刊论文
条目标识符http://ir.sioc.ac.cn/handle/331003/16377
专题中科院有机氟化学重点实验室
通讯作者Huang WY(黄维垣)
推荐引用方式
GB/T 7714
Yang J,Huang WY. Synthesis and characterization of a novel fluorine containing hydrophobically associating polymer[J]. Chin. J. Polym. Sci.,1999,17(3):281-288.
APA 杨进,&黄维垣.(1999).Synthesis and characterization of a novel fluorine containing hydrophobically associating polymer.Chin. J. Polym. Sci.,17(3),281-288.
MLA 杨进,et al."Synthesis and characterization of a novel fluorine containing hydrophobically associating polymer".Chin. J. Polym. Sci. 17.3(1999):281-288.
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