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学科主题: 金属有机化学
题名: Ag-Catalyzed Diastereo- and Enantioselective Synthesis of beta-Substituted Tryptophans from Sulfonylindoles
其他题名: 银催化经吲哚磺酰化合物非对映选择性、对映选择性合成β-取代色氨酸
作者: Zheng BH(郑宝会) ; Ding CH(丁昌华) ; Hou XL(侯雪龙) ; Dai LX(戴立信)
通讯作者: 侯雪龙
刊名: Org. Lett.
发表日期: 2010
卷: 12, 期:8, 页:1688-1691
收录类别: SCI
部门归属: 中国科学院上海有机化学研究所
英文摘要: The asymmetric catalytic synthesis of beta-substituted tryptophan derivatives was realized in high diastereo- and enantioselectivity by the reaction of glycine derivatives with sulfonylindoles in the presence of catalyst derived from AgCl and a commercially available chiral monodentate phosphoramidite ligand. The resulting adduct was readily converted to beta-substituted tryptophan in 95% overall yield for two steps, which presented a highly efficient route to chiral beta-substituted tryptophan.
语种: 英语
相关网址: 查看原文
WOS记录号: WOS:000276562600011
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内容类型: 期刊论文
URI标识: http://ir.sioc.ac.cn/handle/331003/16009
Appears in Collections:金属有机化学国家重点实验室_期刊论文

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Recommended Citation:
Zheng BH,Ding CH,Hou XL,et al. Ag-Catalyzed Diastereo- and Enantioselective Synthesis of beta-Substituted Tryptophans from Sulfonylindoles[J]. Org. Lett.,2010,12(8):1688-1691.
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