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学科主题: 金属有机化学
题名: Palladium-Catalyzed Regio-, Diastereo-, and Enantioselective Allylic Alkylation of Acylsilanes with Monosubstituted Allyl Substrates
其他题名: 钯催化开链酰基硅和单取代烯丙基底物的区域非对映、对映选择性烯丙基烷基化反应
作者: Chen JP(陈建平) ; Ding CH(丁昌华) ; Liu W(刘卫) ; Hou XL(侯雪龙) ; Dai LX(戴立信)
通讯作者: 侯雪龙
刊名: J. Am. Chem. Soc.
发表日期: 2010
卷: 132, 期:44, 页:15493-15495
收录类别: SCI
部门归属: 中国科学院上海有机化学研究所
英文摘要: Acylsilanes as a new type of "hard" carbon prenucleo-phile reacted with monosubstituted allyl reagents under Pd-catalyzed asymmetric allylic alkylation reaction conditions to provide products with high regio-, diastereo-, and enantioselectivities. The usefulness of the protocol has been demonstrated by the ready conversion of the allylated products into the corresponding alcohols, esters, and ketones with retention of stereochemistry as well as by the enantioselective synthesis of cis-3-ethyl-4-phenylpiperidine and cinnamomumolide.
语种: 英语
相关网址: 查看原文
WOS记录号: WOS:000283955600012
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内容类型: 期刊论文
URI标识: http://ir.sioc.ac.cn/handle/331003/15993
Appears in Collections:金属有机化学国家重点实验室_期刊论文

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Recommended Citation:
Chen JP,Ding CH,Liu W,et al. Palladium-Catalyzed Regio-, Diastereo-, and Enantioselective Allylic Alkylation of Acylsilanes with Monosubstituted Allyl Substrates[J]. J. Am. Chem. Soc.,2010,132(44):15493-15495.
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