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学科主题: 金属有机化学
题名: Iron porphyrin-catalyzed olefination of ketenes with diazoacetate for the enantioselective synthesis of allenes
其他题名: Iron porphyrin-catalyzed olefination of ketenes with diazoacetate for the enantioselective synthesis of allenes
作者: Li CY(李传莹) ; Wang XB(王小兵) ; Sun XL(孙秀丽) ; Tang Y(唐勇) ; Zheng JC(郑君成) ; Xu ZH(徐政虎) ; Zhou YG(周永贵) ; Dai LX(戴立信)
通讯作者: 唐勇 ; 周永贵
刊名: J. Am. Chem. Soc.
发表日期: 2007
卷: 129, 期:6, 页:1494-1495
收录类别: SCI
部门归属: 上海有机所
英文摘要: In the presence of Ph3P and catalytic Fe(TCP) Cl, ketenes could react with EDA to give allenes in high yields under neutral conditions for the first time. By employing chiral phosphine instead of PPh3, allenes could be synthesized with high enantioselectivity (93-98% ee) in good yields.
语种: 英语
相关网址: 查看原文
WOS记录号: WOS:000244000700011
Citation statistics:
内容类型: 期刊论文
URI标识: http://ir.sioc.ac.cn/handle/331003/15959
Appears in Collections:金属有机化学国家重点实验室_期刊论文

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Recommended Citation:
Li CY,Wang XB,Sun XL,et al. Iron porphyrin-catalyzed olefination of ketenes with diazoacetate for the enantioselective synthesis of allenes[J]. J. Am. Chem. Soc.,2007,129(6):1494-1495.
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