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学科主题: 有机化学
题名: Synthesis of planar chiral [2.2]paracyclophane monophosphine ligands and their application in the umpolung allylation of aldehydes
其他题名: 平面手性环蕃单膦配体的合成以及在醛的偶极翻转烯丙基化反应中的应用
作者: Zhang TZ(张唐志) ; Dai LX(戴立信) ; Hou XL(侯雪龙)
通讯作者: 侯雪龙
刊名: Tetrahedron-Asymmetry
发表日期: 2007-01-01
卷: 18, 期:2, 页:251-259
收录类别: SCI
部门归属: 上海有机所
英文摘要: Chiral [2.2]paracyclophane monophosphines 8 were synthesized via resolution using chiral palladacycle 10. Chiral phosphinite 5 was also prepared from 4-hydroxy[2.2]paracyclophane. Phosphines 8 and phosphinite 5 were used as the ligand in the umpolung allylation of aldehydes 14 with cyclohexenyl acetate 15, giving homoallyl alcohols 16 in high diastereoselectivity and in moderate to good enantioselectivity. Palladacycle 10 was recovered by treating the palladacycle-phosphine complexes with sodium prolinate, followed by treatment with HCl in high yield. (c) 2007 Elsevier Ltd. All rights reserved.
语种: 英语
相关网址: 查看原文
WOS记录号: WOS:000245167700013
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内容类型: 期刊论文
URI标识: http://ir.sioc.ac.cn/handle/331003/15955
Appears in Collections:金属有机化学国家重点实验室_期刊论文

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Recommended Citation:
Zhang TZ,Dai LX,Hou XL. Synthesis of planar chiral [2.2]paracyclophane monophosphine ligands and their application in the umpolung allylation of aldehydes[J]. Tetrahedron-Asymmetry,2007,18(2):251-259.
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