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学科主题: 有机化学
题名: Highly Diastereoselective Strecker Reaction of Enolizable Aliphatic Sulfinimines
其他题名: 可烯醇化的脂肪族亚磺酰基亚胺的高非对映选择性Strecker反应
作者: Li BF(李斌峰) ; Yuan K(苑可) ; Zhang MJ(张明杰) ; Wu H(吴昊) ; Dai LX(戴立信) ; Wang QR(王全瑞) ; Hou XL(侯雪龙)
通讯作者: 侯雪龙
刊名: J. Org. Chem.
发表日期: 2003
卷: 68, 期:16, 页:6264-6267
收录类别: SCI
部门归属: 中国科学院上海有机化学研究所金属有机化学开放实验室; 复旦大学化学系
英文摘要: The reaction of chiral sulfinimines 1c-g derived from aliphatic aldehydes with TMSCN in the presence of CsF gave α-amino nitriles in high diastereoselectivity and yield. Α,β-Diamino acid derivatives were also obtained in high diastereoselectivity from the reaction of 2-aziridinesulfinimines 1h and 1i followed by ring-opening of the products with thiophenol. The presence of hydrogen at the α-position of the C=N double bond is crucial in this TMSCN addition reaction.
语种: 英语
相关网址: 查看原文
WOS记录号: WOS:000184552500026
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内容类型: 期刊论文
URI标识: http://ir.sioc.ac.cn/handle/331003/15887
Appears in Collections:金属有机化学国家重点实验室_期刊论文

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Recommended Citation:
Li BF,Yuan K,Zhang MJ,et al. Highly Diastereoselective Strecker Reaction of Enolizable Aliphatic Sulfinimines[J]. J. Org. Chem.,2003,68(16):6264-6267.
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