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Asymmetric Catalysis with Chiral Ferrocene Ligands
Alternative Title手性二茂铁为配体的不对称催化
Dai LX(戴立信); Tu T(涂涛); You SL(游书力); Deng WP(邓卫平); Hou XL(侯雪龙)
Source PublicationAccounts Chem. Res.
AbstractChiral ferrocene ligands have been widely used in asymmetric catalysis. The advantages of using ferrocene as a scaffold for chiral ligands are described, particularly those regarding planar chirality, rigid bulkiness, and ease of derivatization. The role of planar chirality in 1,2- and 1,1¢-disubstituted ferrocene systems is discussed. By using a bulky ferrocene fragment, novel ferrocene ligands were designed, and high enantioselectivity and regioselectivity were achieved in the allylic substitution reaction of monosubstituted allyl substrates. Using the tunable electronic properties of a diphosphine-oxazoline ferrocenyl ligand, the regioselectivity of the intermolecular asymmetric Heck reaction was also examined.
Subject Area金属有机化学
Indexed BySCI
WOS IDWOS:000185430400003
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Document Type期刊论文
Corresponding AuthorHou XL(侯雪龙)
Recommended Citation
GB/T 7714
Dai LX,Tu T,You SL,et al. Asymmetric Catalysis with Chiral Ferrocene Ligands[J]. Accounts Chem. Res.,2003,36(9):659-667.
APA 戴立信,涂涛,游书力,邓卫平,&侯雪龙.(2003).Asymmetric Catalysis with Chiral Ferrocene Ligands.Accounts Chem. Res.,36(9),659-667.
MLA 戴立信,et al."Asymmetric Catalysis with Chiral Ferrocene Ligands".Accounts Chem. Res. 36.9(2003):659-667.
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