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学科主题: 金属有机化学
题名: Asymmetric Catalysis with Chiral Ferrocene Ligands
其他题名: 手性二茂铁为配体的不对称催化
作者: Dai LX(戴立信) ; Tu T(涂涛) ; You SL(游书力) ; Deng WP(邓卫平) ; Hou XL(侯雪龙)
通讯作者: 侯雪龙
刊名: Accounts Chem. Res.
发表日期: 2003
卷: 36, 期:9, 页:659-667
收录类别: SCI
部门归属: 中国科学院上海有机化学研究所金属有机化学开放实验室
英文摘要: Chiral ferrocene ligands have been widely used in asymmetric catalysis. The advantages of using ferrocene as a scaffold for chiral ligands are described, particularly those regarding planar chirality, rigid bulkiness, and ease of derivatization. The role of planar chirality in 1,2- and 1,1¢-disubstituted ferrocene systems is discussed. By using a bulky ferrocene fragment, novel ferrocene ligands were designed, and high enantioselectivity and regioselectivity were achieved in the allylic substitution reaction of monosubstituted allyl substrates. Using the tunable electronic properties of a diphosphine-oxazoline ferrocenyl ligand, the regioselectivity of the intermolecular asymmetric Heck reaction was also examined.
语种: 英语
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WOS记录号: WOS:000185430400003
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内容类型: 期刊论文
URI标识: http://ir.sioc.ac.cn/handle/331003/15885
Appears in Collections:金属有机化学国家重点实验室_期刊论文

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Recommended Citation:
Dai LX,Tu T,You SL,et al. Asymmetric Catalysis with Chiral Ferrocene Ligands[J]. Accounts Chem. Res.,2003,36(9):659-667.
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