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学科主题: 金属有机化学
题名: On the Regioselectivity of Asymmetric Intermolecular Heck Reaction with Planar Chiral Diphosphine-oxazoline Ferrocene Ligands
其他题名: 平面手性双膦-恶唑啉二茂铁为配体的不对称Heck反应中的区域选择性
作者: Tu T(涂涛) ; Deng WP(邓卫平) ; Hou XL(侯雪龙) ; Dai LX(戴立信) ; Dong XC(董喜成)
通讯作者: 侯雪龙
刊名: Chem.-Eur. J.
发表日期: 2003-01-01
卷: 9, 期:13, 页:3073-3081
收录类别: SCI
部门归属: 中国科学院上海有机化学研究所金属有机化学开放实验室
英文摘要: A series of novel planar chiral diphosphine-oxazoline ferrocenyl ligands were synthesized and used efficiently in the palladium catalyzed asymmetric intermolecular Heck reaction of 2,3-dihydrofuran with aryl triflate and cyclohexenyl triflate. The tunning of regioselectivity was realized by using different palladium precursors and changing the electronic factor of the ligands. A plausible rationale based on the existed mechanism was provided.
语种: 英语
相关网址: 查看原文
内容类型: 期刊论文
URI标识: http://ir.sioc.ac.cn/handle/331003/15883
Appears in Collections:金属有机化学国家重点实验室_期刊论文

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Recommended Citation:
Tu T,Deng WP,Hou XL,et al. On the Regioselectivity of Asymmetric Intermolecular Heck Reaction with Planar Chiral Diphosphine-oxazoline Ferrocene Ligands[J]. Chem.-Eur. J.,2003,9(13):3073-3081.
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