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学科主题: 金属有机化学
题名: Novel ferrocene modified P,N-ligands for enantioselective palladium-catalyzed allylic substituion reactions.
其他题名: 新型二茂铁修饰的 P,N 配体及对映选择性钯催化烯丙基取代反应
作者: You SL(游书力) ; Hou XL(侯雪龙) ; Dai LX(戴立信)
通讯作者: 侯雪龙
刊名: J. Organomet. Chem.
发表日期: 2001-01-01
卷: 637-639, 页:762-766
收录类别: SCI
部门归属: 中国科学院上海有机化学研究所金属有机化学开放实验室
英文摘要: Novel ferrocene modified P,N-ligands(R,R,Sp)-8and (S,S,Sp)-9 were synthesized conveniently from enantiopure cyclohexane diamine and (Sp)-2-phosphinoferrocenyl carboxylic acid. Theywere used as chiral ligands for palladium-catalyzed allylic substitutions of rac-1,3-diphenylprop-2-enyl acetate with dimethylmalonate and benzylamine (R,R,Sp)-8was found to be a better ligand containing matched chiralities (central chirality and planar chirality) and showed a higher enantioselectivity.
语种: 英语
相关网址: 查看原文
内容类型: 期刊论文
URI标识: http://ir.sioc.ac.cn/handle/331003/15863
Appears in Collections:金属有机化学国家重点实验室_期刊论文

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Recommended Citation:
You SL,Hou XL,Dai LX. Novel ferrocene modified P,N-ligands for enantioselective palladium-catalyzed allylic substituion reactions.[J]. J. Organomet. Chem.,2001,637-639:762-766.
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