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学科主题: 有机氟化学
题名: Allylation of Imines with Allyltrimethylsilane and Experimental Evidences for a Fluoride-Triggered Autocatalysis Mechanism of the Sakurai-Hosomi Reaction
其他题名: 三甲基烯丙基硅烷对亚胺的烯丙基化反应及氟引发的自催化机理的实验证据
作者: Wang DK(王德坤) ; Zhou YG(周永贵) ; Tang Y(唐勇) ; Hou XL(侯雪龙) ; Dai LX(戴立信)
通讯作者: 侯雪龙
刊名: J. Org. Chem.
发表日期: 1999
卷: 64, 页:4233-4237
收录类别: SCI
部门归属: 中国科学院上海有机化学研究所金属有机化学开放实验室
英文摘要: This article reports the reaction of allyltrimethylsilane 1 with aldimines 2 in the presence of tetra-n-butylammonium fluoride to give the corresponding homoallylamines 3 in moderate to excellent yields. The allylation mechanism of imines as well as that of aldehydes can be reasonably interpreted by a fluoride-triggered autocatalytic procedure.
语种: 英语
相关网址: 查看原文
WOS记录号: WOS:000080849000006
Citation statistics:
内容类型: 期刊论文
URI标识: http://ir.sioc.ac.cn/handle/331003/15817
Appears in Collections:金属有机化学国家重点实验室_期刊论文

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Recommended Citation:
Wang DK,Zhou YG,Tang Y,et al. Allylation of Imines with Allyltrimethylsilane and Experimental Evidences for a Fluoride-Triggered Autocatalysis Mechanism of the Sakurai-Hosomi Reaction[J]. J. Org. Chem.,1999,64:4233-4237.
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