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学科主题: 生命有机化学
题名: Assembly of Substituted 1H-Benzimidazoles and 1,3-Dihydrobenzimidazol-2-ones via CuI/L-Proline Catalyzed Coupling of Aqueous Ammonia with 2-Iodoacetanilides and 2-Iodophenylcarbamates
其他题名: 碘化亚铜/脯氨酸催化的氨水与2-碘乙酰苯胺或2-碘苯胺甲酸酯偶联反应构建1H-苯并咪唑和1,3-二氢苯并咪唑-2-酮
作者: Diao XQ(刁小琼) ; Wang YJ(王余吉) ; Jiang YW(蒋咏文) ; Ma DW(马大为)
通讯作者: 马大为
刊名: J. Org. Chem.
发表日期: 2009
卷: 74, 期:20, 页:7974-7977
收录类别: SCI
部门归属: 复旦大学; 上海有机所
英文摘要: CuI/L-proline catalyzed coupling of aqueous ammonia with 2-iodoacetanilides and 2-iodophenylcarbamates affords the aryl amination products at room temperature, which undergo in situ additive cyclization under acidic conditions or heating to give substituted 1H-benzimidazoles and 1,3-dihydrobenzimidazol-2-ones, respectively. A wide range of functional groups including ketone, nitro, iodo, bromo, and ester are tolerated under these reaction conditions, providing these heterocycles with great diversity.
语种: 英语
相关网址: 查看原文
WOS记录号: WOS:000270504900048
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内容类型: 期刊论文
URI标识: http://ir.sioc.ac.cn/handle/331003/15597
Appears in Collections:生命有机化学国家重点实验室_期刊论文

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Recommended Citation:
Diao XQ,Wang YJ,Jiang YW,et al. Assembly of Substituted 1H-Benzimidazoles and 1,3-Dihydrobenzimidazol-2-ones via CuI/L-Proline Catalyzed Coupling of Aqueous Ammonia with 2-Iodoacetanilides and 2-Iodophenylcarbamates[J]. J. Org. Chem.,2009,74(20):7974-7977.
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