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Enantioselective organocatalytic Michael addition of malonates to alpha,beta-unsaturated aldehydes in water
Alternative Title水相有机催化的对映选择性的丙二酸酯对α,β-不饱和醛的Michael加成反应
Ma AQ(马安琪); Zhu SL(朱少林); Ma DW(马大为)
2008
Source PublicationTetrahedron Lett.
ISSN0040-4039
Volume49Issue:19Pages:3075-3077
AbstractThe Michael addition of malonates to alpha,beta-unsaturated aldehydes catalyzed by O-TMS protected diphenylprolinols and acetic acid in water occurs at 0 degrees C to rt. In most cases, the reaction runs to completion in less than 24 h. A wide range of aldehydes including beta-aryl, beta-alkyl and beta-alkenyl acroleins are found to be compatible with these conditions, providing the corresponding adducts in good yields and with good to excellent enantioselectivities. (C) 2008 Elsevier Ltd. All rights reserved.
Subject Area生命有机化学
Department上海有机所
URL查看原文
Indexed BySCI
Language英语
WOS IDWOS:000255774700011
Citation statistics
Cited Times:61[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://ir.sioc.ac.cn/handle/331003/15577
Collection生命有机化学国家重点实验室
Corresponding AuthorMa DW(马大为)
Recommended Citation
GB/T 7714
Ma AQ,Zhu SL,Ma DW. Enantioselective organocatalytic Michael addition of malonates to alpha,beta-unsaturated aldehydes in water[J]. Tetrahedron Lett.,2008,49(19):3075-3077.
APA 马安琪,朱少林,&马大为.(2008).Enantioselective organocatalytic Michael addition of malonates to alpha,beta-unsaturated aldehydes in water.Tetrahedron Lett.,49(19),3075-3077.
MLA 马安琪,et al."Enantioselective organocatalytic Michael addition of malonates to alpha,beta-unsaturated aldehydes in water".Tetrahedron Lett. 49.19(2008):3075-3077.
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