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学科主题: 生命有机化学
题名: Enantioselective organocatalytic Michael addition of malonates to alpha,beta-unsaturated aldehydes in water
其他题名: 水相有机催化的对映选择性的丙二酸酯对α,β-不饱和醛的Michael加成反应
作者: Ma AQ(马安琪) ; Zhu SL(朱少林) ; Ma DW(马大为)
通讯作者: 马大为
刊名: Tetrahedron Lett.
发表日期: 2008
卷: 49, 期:19, 页:3075-3077
收录类别: SCI
部门归属: 上海有机所
英文摘要: The Michael addition of malonates to alpha,beta-unsaturated aldehydes catalyzed by O-TMS protected diphenylprolinols and acetic acid in water occurs at 0 degrees C to rt. In most cases, the reaction runs to completion in less than 24 h. A wide range of aldehydes including beta-aryl, beta-alkyl and beta-alkenyl acroleins are found to be compatible with these conditions, providing the corresponding adducts in good yields and with good to excellent enantioselectivities. (C) 2008 Elsevier Ltd. All rights reserved.
语种: 英语
相关网址: 查看原文
WOS记录号: WOS:000255774700011
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内容类型: 期刊论文
URI标识: http://ir.sioc.ac.cn/handle/331003/15577
Appears in Collections:生命有机化学国家重点实验室_期刊论文

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Recommended Citation:
Ma AQ,Zhu SL,Ma DW. Enantioselective organocatalytic Michael addition of malonates to alpha,beta-unsaturated aldehydes in water[J]. Tetrahedron Lett.,2008,49(19):3075-3077.
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