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学科主题: 生命有机化学
题名: Asymmetric total syntheses of marine cyclic depsipeptide halipeptins A-D synthesis; unnatural amino acids
其他题名: 一类具有潜在抗炎活性环酯肽halipeptins A-D的全合成
作者: Yu SY(俞寿云) ; Pan XH(潘仙华) ; Ma DW(马大为)
通讯作者: 马大为
刊名: Chem.-Eur. J.
发表日期: 2006-01-01T00:00:00Z
卷: 12, 期:25, 页:6572-6584
收录类别: SCI
部门归属: 上海有机所; 复旦大学
英文摘要: Halipeptins A-D (1a-d) are a family of natural cyclic depsipeptides isolated from marine sponges. Total syntheses of these four compounds are detailed in this report. The key elements in this synthesis include the elaboration of the polysubstituted decanoic acid parts by two asymmetric aldol reactions, assembly of the N-methyl-delta-hydroxyisoleucine residue by using either aza-Claisen rearrangement or methylation of aspartates as the key steps, and macrocyclization at the polysubstituted decanoic acid alanine site.
语种: 英语
相关网址: 查看原文
内容类型: 期刊论文
URI标识: http://ir.sioc.ac.cn/handle/331003/15513
Appears in Collections:生命有机化学国家重点实验室_期刊论文

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Recommended Citation:
Yu SY,Pan XH,Ma DW. Asymmetric total syntheses of marine cyclic depsipeptide halipeptins A-D synthesis; unnatural amino acids[J]. Chem.-Eur. J.,2006,12(25):6572-6584.
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