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学科主题: 金属有机化学
题名: Synthesis of aryl sulfones via L-proline-promoted CuI-catalyzed coupling reaction of aryl halides with sulfinic acid salts
其他题名: L-脯氨酸促进的、CuI催化的芳基卤代物和烃基亚磺酸钠反应合成芳基砜
作者: Zhu W(竺伟) ; Ma DW(马大为)
通讯作者: 马大为
刊名: J. Org. Chem.
发表日期: 2005
卷: 70, 期:7, 页:2696-2700
收录类别: SCI
部门归属: 上海有机所; 复旦大学
英文摘要: The CuI/L-proline sodium salt catalyzed coupling reaction of aryl halides with sulfinic acid salts readily occurs at 80-95 degrees C in DMSO to give the corresponding aryl sulfones in good to excellent yields. This process is well-tolerated by a wide range of functional groups including hydroxyl, amino, acetanilide, ketone, ester, and nitrile. Using this method, 4-phenylsulfonyl- and 4-methanesulfonyl-substituted L-phenylalanine derivatives are prepared.
语种: 英语
相关网址: 查看原文
WOS记录号: WOS:000227928200035
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内容类型: 期刊论文
URI标识: http://ir.sioc.ac.cn/handle/331003/15493
Appears in Collections:生命有机化学国家重点实验室_期刊论文

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Recommended Citation:
Zhu W,Ma DW. Synthesis of aryl sulfones via L-proline-promoted CuI-catalyzed coupling reaction of aryl halides with sulfinic acid salts[J]. J. Org. Chem.,2005,70(7):2696-2700.
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