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学科主题: 生命有机化学
题名: Prepartion of syn-δ-Hydroxy-β-amino esters via an intramolecular hydrogen bond directed diastereoselective hydrogenation. Total synthesis of (3S,4aS,6R,8S)-hyperaspine
其他题名: 分子内氢键诱导的非对映选择性氢化制备顺式δ-羟基-β-氨基酯(3S,4aS,6R,8S)-hyperaspine的全合成
作者: Zhu W(朱伟) ; Ma DW(马大为)
通讯作者: 马大为
刊名: Org. Lett.
发表日期: 2003-01-01T00:00:00Z
卷: 5, 期:26, 页:5063-5066
收录类别: SCI
部门归属: 中国科学院上海有机化学研究所生命有机国家开放实验室
英文摘要: Hydrogenation of δ-hydroxy-β-ketoester-derived enamines 8 produces syn-δ-hydroxy-β-amino esters 9 diastereoselectively, which may be directed by the formation of an intramolecular hydrogen bond between the δ-hydroxyl and β-amino groups. By using this method and a dieckmann reaction as the key steps,(3S,4aS,6R,8S)-hyperaspine, a new type of ladybird alkaloid, is synthesized.
语种: 英语
相关网址: 查看原文
内容类型: 期刊论文
URI标识: http://ir.sioc.ac.cn/handle/331003/15443
Appears in Collections:生命有机化学国家重点实验室_期刊论文

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Recommended Citation:
Zhu W,Ma DW. Prepartion of syn-δ-Hydroxy-β-amino esters via an intramolecular hydrogen bond directed diastereoselective hydrogenation. Total synthesis of (3S,4aS,6R,8S)-hyperaspine[J]. Org. Lett.,2003,5(26):5063-5066.
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