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学科主题: 生命有机化学
题名: Asymmetric synthesis of (S)-1-aminoindan-1,5-dicarboxylic acid and related analogues via intramolecular acylation of enantiopure α,α-disubstituted amino acids
其他题名: 通过光学纯的α,α-二取代氨基酸的分子内酰化反应不对称得合成(S)-1-氨基-1,5-二羧基茚机相应的类似物
作者: Ma DW(马大为) ; Ding K(丁克) ; Tian HQ(田红旗) ; Wang BM(王保民) ; Cheng DL(程东亮)
通讯作者: 马大为
刊名: Tetrahedron-Asymmetry
发表日期: 2002-01-01
卷: 13, 期:9, 页:961-969
收录类别: SCI
部门归属: 中国科学院上海有机化学研究所生命有机化学实验室
英文摘要: α,α-Disubstituted amino acid derivatives are synthesized either by a self-regeneration of stereocenter strategy or using the asymmetric strecker reaction alkylation method. Of the four types of substrates tested for intramolecular acylation. Those with a 4-alkoxyl group do not react. Those with a 4-bromo substituent give lower conversions. While those without a 4-subsitutent of with a 4-methyl grou work well to give the desired cyclization products. Based on these investigations, a new route for preparing (S)-1-aminoindan-1,5-dicarboxylic acid (S)-AIDA and its analogues was developed.
语种: 英语
相关网址: 查看原文
内容类型: 期刊论文
URI标识: http://ir.sioc.ac.cn/handle/331003/15425
Appears in Collections:生命有机化学国家重点实验室_期刊论文

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Recommended Citation:
Ma DW,Ding K,Tian HQ,et al. Asymmetric synthesis of (S)-1-aminoindan-1,5-dicarboxylic acid and related analogues via intramolecular acylation of enantiopure α,α-disubstituted amino acids[J]. Tetrahedron-Asymmetry,2002,13(9):961-969.
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