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学科主题: 生命有机化学
题名: Synthesis of enantiopure N-protected 4,5-disubstituted 3-pyrrolidinones and N-protected 2,5-disubstituted 3-pyrrolidinones via the dieckmann reaction of dicarbonyl compounds derived from enantiopureβ-amino esters
其他题名: 基于光学纯β-氨基酸衍生的二羰基化合物的狄克曼反应对于光学纯的N-保护4,5-二取代-3-吡咯烷酮及N-保护2,5-二取代-3-吡咯烷酮的合成
作者: Wang Y(王悦) ; Ma DW(马大为)
通讯作者: 马大为
刊名: Tetrahedron-Asymmetry
发表日期: 2001-01-01
卷: 12, 期:5, 页:725-730
收录类别: SCI
部门归属: 中国科学院上海有机化学研究所生命有机国家开放实验室
英文摘要: Under the action of KHMDS in THF solvent the Dieckmann reaction of dicarbonyl compounds derived from enantiopure β-amino esters provides enantiopure N-protected 4,5-disubstituted 3-pyrrolidinones, whereas N-protected 2,5-disubstituted 3-pyrrolidinones formed in reactions mediated by tert-BuOK in DMF or toluene. Reduction of these pyrrolidinones afforded enantiopure polysubstituted pyrrolidines.
语种: 英语
相关网址: 查看原文
内容类型: 期刊论文
URI标识: http://ir.sioc.ac.cn/handle/331003/15391
Appears in Collections:生命有机化学国家重点实验室_期刊论文

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Recommended Citation:
Wang Y,Ma DW. Synthesis of enantiopure N-protected 4,5-disubstituted 3-pyrrolidinones and N-protected 2,5-disubstituted 3-pyrrolidinones via the dieckmann reaction of dicarbonyl compounds derived from enantiopureβ-amino esters[J]. Tetrahedron-Asymmetry,2001,12(5):725-730.
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