中国科学院上海有机化学研究所机构知识库
Advanced  
SIOC OpenIR  > 金属有机化学国家重点实验室  > 期刊论文
学科主题: 金属有机化学
题名: Multi-center nature of ethylene polymerization catalysts based on 2,6-bis(imino)pyridyl complexes of iron and cobalt distribution
其他题名: 2,6-二亚胺吡啶铁钴配合物作为乙烯聚合物催化剂的多中心性质
作者: Kissin, Y. V. ; Qian ZT(钱长涛) ; Xie GY(谢光勇) ; Chen YF(陈耀峰)
通讯作者: Kissin, Y. V. ; 钱长涛
刊名: J. Polym. Sci. Pol. Chem.
发表日期: 2006-01-01
卷: 44, 期:21, 页:6159-6170
收录类别: SCI
部门归属: Rutgers State Univ, Dept Chem, Piscataway, NJ 08854 USA.; 中科院上海有机化学研究所
英文摘要: 2,6-Bis(imino)pyridyl complexes of Fe and Co in combination with methylalumoxane form very active homogeneous catalytic systems for polymerization of ethylene. GPC analysis of the polymers prepared with the complexes indicates that the Co complexes produce single-center catalysts whereas the Fe complexes produce catalysts with numerous types of active centers. Different centers in the latter catalyst systems respond differently to reaction conditions such as the reaction duration, the [MAO]:[Fe] ratio, the ethylene concentration, etc. The article examines the effects of reaction variables on the performance of both types of catalysts and proposes an explanation for the complex behavior of the catalysts derived from the Fe complexes. (c) 2006 Wiley Periodicals, Inc.
语种: 英语
相关网址: 查看原文
内容类型: 期刊论文
URI标识: http://ir.sioc.ac.cn/handle/331003/15287
Appears in Collections:金属有机化学国家重点实验室_期刊论文

Files in This Item: Download All
File Name/ File Size Content Type Version Access License
2006003.pdf(265KB)----开放获取--View Download

Recommended Citation:
Kissin, Y. V.,Qian ZT,Xie GY,et al. Multi-center nature of ethylene polymerization catalysts based on 2,6-bis(imino)pyridyl complexes of iron and cobalt distribution[J]. J. Polym. Sci. Pol. Chem.,2006,44(21):6159-6170.
Service
Recommend this item
Sava as my favorate item
Show this item's statistics
Export Endnote File
Google Scholar
Similar articles in Google Scholar
[Kissin, Y. V.]'s Articles
[钱长涛]'s Articles
[谢光勇]'s Articles
CSDL cross search
Similar articles in CSDL Cross Search
[Kissin, Y. V.]‘s Articles
[钱长涛]‘s Articles
[谢光勇]‘s Articles
Related Copyright Policies
Null
Social Bookmarking
Add to CiteULike Add to Connotea Add to Del.icio.us Add to Digg Add to Reddit
文件名: 2006003.pdf
格式: Adobe PDF
此文件暂不支持浏览
所有评论 (0)
暂无评论
 
评注功能仅针对注册用户开放,请您登录
您对该条目有什么异议,请填写以下表单,管理员会尽快联系您。
内 容:
Email:  *
单位:
验证码:   刷新
您在IR的使用过程中有什么好的想法或者建议可以反馈给我们。
标 题:
 *
内 容:
Email:  *
验证码:   刷新

Items in IR are protected by copyright, with all rights reserved, unless otherwise indicated.

 

 

Valid XHTML 1.0!
Powered by CSpace