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学科主题: 金属有机化学
题名: Zur elektronenstruktur metallorganischer komplexe der f-Elemente LVI. Parametrische analyse der kristallfedl-aufspaltungsmuster pseudo-trigonal-bipyramidal koordinierter O-und P-donorfunktionalisierter ethylcyclopentadienyl-Komplexe des Neodym(III)
其他题名: 畸变三角双锥甲氧乙基环戊二烯基配位的Neodym(III)配合物的吸收光谱
作者: Hanns-Dieter Amberger ; Hauke Reddmann ; Hans H. Karsch ; Volker W. Graf ; Qian ZT(钱长涛) ; Wang B(王兵)
通讯作者: Hanns-Dieter Amberger
刊名: J. Organomet. Chem.
发表日期: 2003-01-01T00:00:00Z
卷: 677, 期:1-2, 页:35-45
收录类别: SCI
部门归属: 德国汉堡大学; 中国科学院上海有机化学研究所金属有机化学开放实验室
英文摘要: The absorption spectra of pseudo trigonal bipyramidally coordinated Nd(η5-C5H4CH2CH2OMe)3 (1) and Nd(η5-C5H4CH2CH2PMe)3 (2) have been measured at room and low temperature. From the spectra obtained, truncated crystal field (CF) splitting patterns of these compounds are derived, and simulated by fitting the oarameters of a phenomenological Hamiltonian. For 55 and 53 assignments, respectively, reduced r.m.s. deviations of 31 and 23 cm-1 are achieved foe complexes 1 and 2. the parameter derived allow the estimation of the crystal field strength experienced by the Nd+3 central ions of compounds 1 and 2, the insertion of these complexes into truncated empirical nephelauxetic and relativistic nephelauxetic series, and the setup of their experimentally-based non-relativistic and relativistic molecular orbital schemes in the f range.
语种: 英语
相关网址: 查看原文
内容类型: 期刊论文
URI标识: http://ir.sioc.ac.cn/handle/331003/15271
Appears in Collections:金属有机化学国家重点实验室_期刊论文

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Recommended Citation:
Hanns-Dieter Amberger,Hauke Reddmann,Hans H. Karsch,et al. Zur elektronenstruktur metallorganischer komplexe der f-Elemente LVI. Parametrische analyse der kristallfedl-aufspaltungsmuster pseudo-trigonal-bipyramidal koordinierter O-und P-donorfunktionalisierter ethylcyclopentadienyl-Komplexe des Neodym(III)[J]. J. Organomet. Chem.,2003,677(1-2):35-45.
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