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学科主题: 金属有机化学
题名: Synthesis and crystal structure of one carbon-atom bridged lutetium complex [Ph^2C(Flu)(Cp)]LuN(TMS)^2 and catalytic activity for polymerization of polar monomers
其他题名: 单原子桥联[Ph^2C(Flu)(Cp)]LuN(TMS)^2 的合成晶体结构和对极单体聚合的催化性质
作者: Qian ZT(钱长涛) ; Nie WL(聂万丽) ; Chen YF(陈耀峰) ; Sun J(孙杰)
通讯作者: 钱长涛
刊名: J. Organomet. Chem.
发表日期: 2002-01-01
卷: 645, 期:1-2, 页:82-86
收录类别: SCI
部门归属: 中国科学院上海有机化学研究所金属有机化学开放实验室
英文摘要: The one-carbon atom bridged amide complex [Ph^2C(Flu)(Cp)]LuN(TMS)^2(2) (Flu=C^13H^8, Cp=C^5H^4, TMS=SiMe^3) has been synthesized by reaction of its chloride precursor with LiN(TMS)^2 in toluene. An X-ray structure of the amide complex 2 exhibits apparedntly intramolecular βSi- C agostic interaction with Lu. Polymerzation of methyl methacrylate (MMA) and lactones with this complex has also been investigated.
语种: 英语
相关网址: 查看原文
内容类型: 期刊论文
URI标识: http://ir.sioc.ac.cn/handle/331003/15251
Appears in Collections:金属有机化学国家重点实验室_期刊论文

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Recommended Citation:
Qian ZT,Nie WL,Chen YF,et al. Synthesis and crystal structure of one carbon-atom bridged lutetium complex [Ph^2C(Flu)(Cp)]LuN(TMS)^2 and catalytic activity for polymerization of polar monomers[J]. J. Organomet. Chem.,2002,645(1-2):82-86.
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