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学科主题: 金属有机化学
题名: The first example of a dinuclear anionic lanthanoidocene complex: [K(18-crown-6){(C^13H^8)CPh^2(C^5H^4Nd(BH^4)^2}]^2.C^4H^8O^2
其他题名: 首例茂稀土双核阴离子化合物
作者: Qian ZT(钱长涛) ; Nie WL(聂万丽) ; Sun J(孙杰)
通讯作者: 钱长涛
刊名: J. Organomet. Chem.
发表日期: 2001-01-01
卷: 626, 期:1-2, 页:171-175
收录类别: SCI
部门归属: 中国科学院上海有机化学研究所金属有机化学开放实验室
英文摘要: The first dinuclear anionic lanthanocene compound is described. By reaction of [Nd(BH^4)^3 with K^2[FluCPh^2Cp] in THF solution in the presence of 18-crown-6 ether we got an anionic complex[K(18-crown-6){(C^13H^8)CPh^2(C^5H^4Nd(BH^4)^2}]^2.C^4H^8O^2 The crystal structure of this complex was determined and indicated that this anionic compound crystallized in a binuclear fashion. It consists of three parts: the two discrete anions of {(C^13H^8)CPh^2(C^5H^4Nd(BH^4)^2}-moiety is connected by the cation of [K(18-crown-6)]~+^2.C^4H^8O^2 through a weak η~2 interaction of the Flu moieties with the K~+ cations.
语种: 英语
相关网址: 查看原文
内容类型: 期刊论文
URI标识: http://ir.sioc.ac.cn/handle/331003/15241
Appears in Collections:金属有机化学国家重点实验室_期刊论文

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Recommended Citation:
Qian ZT,Nie WL,Sun J. The first example of a dinuclear anionic lanthanoidocene complex: [K(18-crown-6){(C^13H^8)CPh^2(C^5H^4Nd(BH^4)^2}]^2.C^4H^8O^2[J]. J. Organomet. Chem.,2001,626(1-2):171-175.
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