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学科主题: 金属有机化学
题名: Polymeric chain structures of substituted (Dimethylfluorenylsilyl)cyclopentadienyl lithium and sodium compounds
其他题名: 具有聚合链结构的二甲基异基硅基取代环戊二烯锂和钠化合物
作者: Nie WL(聂万丽) ; Qian ZT(钱长涛) ; Chen YF(陈耀峰) ; Sun J(孙杰)
通讯作者: 钱长涛
刊名: Organometallics
发表日期: 2001
卷: 20, 期:26, 页:5780-5783
收录类别: SCI
部门归属: 中国科学院上海有机化学研究所金属有机化学开放实验室
英文摘要: Summary: reaction of the dimethylsily-bridged flourene cyclopentadiene ligand with 1 equiv of n-butylithium or sodium hydride smoothly afforded the corresponding monoalkali=metal salts [(FluMe^2Si)Cp]M.(THF)^n(Cp=C^5H^4Flu=C^13H^9)(M=Li(1),n=0; M=Na(2), n=1).Complexes 1 and 2 were characterized by single crystal X-ray structural analyses. These revealed that both of then have similar linear polymeric structural aggregate types in the solid state. In complexes 1 and 2, the fluorenyldimethylsily groups attached to the cyclopentadienyl rings are arranged in gaps and oriented on the same side of the multideck chain.
语种: 英语
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WOS记录号: WOS:000172939800048
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内容类型: 期刊论文
URI标识: http://ir.sioc.ac.cn/handle/331003/15237
Appears in Collections:金属有机化学国家重点实验室_期刊论文

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Recommended Citation:
Nie WL,Qian ZT,Chen YF,et al. Polymeric chain structures of substituted (Dimethylfluorenylsilyl)cyclopentadienyl lithium and sodium compounds[J]. Organometallics,2001,20(26):5780-5783.
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