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学科主题: 金属有机化学
题名: Co-ordinatively unsaturated neodymium hydrides, stability in solution
其他题名: 配位不饱和的钕的氢化物, 溶液中的稳定性
作者: Marc Visseaux ; Denise Baudry ; Alain Dormond ; Qian ZT(钱长涛)
通讯作者: Marc Visseaux
刊名: J. Organomet. Chem.
发表日期: 1999
卷: 574, 页:213-218
收录类别: SCI
部门归属: 法国金属有机实验室; 中国科学院上海有机化学研究所金属有机化学开放实验室
英文摘要: The tris-alkyborohydride Cp^~Q NdHBEt^3 (Cp^Q=C^5H^4CH^2CH^2OCH^3) obtained by reaction of NaHBEt^3 with CP^2~QNdCl is fairly stable in solution whereas the hydride CP^2~Q NdH formed from Cp^2~QNdCl and NAH or by hydrogenolsis of Cp^2~Q NDR (R=CH^2SiMe^3 or CH(SiMe^3)^2) is a species of very short life, undergoing rearrangement to Cp^3QNd. This transient hydride is not observed but can be trapped with ketones-propanone or pivalone. Leading to the alkoxides Cp^2~QNdOCHR^2(R'=Me or CM^3). The same alkoxides are obtained from Cp^2~QNdHBEt^3.
语种: 英语
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WOS记录号: WOS:000079056500002
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内容类型: 期刊论文
URI标识: http://ir.sioc.ac.cn/handle/331003/15219
Appears in Collections:金属有机化学国家重点实验室_期刊论文

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Recommended Citation:
Marc Visseaux,Denise Baudry,Alain Dormond,et al. Co-ordinatively unsaturated neodymium hydrides, stability in solution[J]. J. Organomet. Chem.,1999,574:213-218.
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