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学科主题: 金属有机化学
题名: Stereoselective synthesis and structural characterization of rac-planar chiral bis(2-methoxyethylindenyl)lanthanum and yttrium tetrahydroborates
其他题名: 平面手性双(2-甲氧乙基茚)镧氢化物外消旋体的立体选择性合成和结构测定
作者: Qian ZT(钱长涛) ; Zou G(邹刚) ; Nie WL(聂万丽) ; Sun J(孙杰) ; Dmitri A. ; Lemenovskii ; Maxim V. Borzov
通讯作者: 钱长涛
刊名: Polyhedron
发表日期: 2000
卷: 19, 期:16-17, 页:1955-1959
收录类别: SCI
部门归属: 中国科学院上海有机化学研究所金属有机化学开放实验室
英文摘要: Racemic planar chiral metallocenes bis(2-methoxyethylindenyl) yttrium and lanthanum tetrahydroborates (MeOCH^2CH^2C^9H^6)^2Lnμ2-H)nBH^4-n (Lu = Y, n = 2(1); Ln = La, n = 3, (2)) have been stereoselectively isolated in high yield by reaction of the corresponding lanthanoeene chlorides with sodium borohydride in THF at room temperature. The two complexes have been fully characterized by elemental analyses, MS. ~1H NMR and IR spectra. The tetrahydroborate ion has been identified as slipped bidentate (μ^2-H)^2BH^2 and tridentate (μ^2H)^3BH ligands in I and 2, respectively. 2000 Elsevier Science Ltd. All rights reserved.
语种: 英语
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WOS记录号: WOS:000089771100010
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内容类型: 期刊论文
URI标识: http://ir.sioc.ac.cn/handle/331003/15211
Appears in Collections:金属有机化学国家重点实验室_期刊论文

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Recommended Citation:
Qian ZT,Zou G,Nie WL,et al. Stereoselective synthesis and structural characterization of rac-planar chiral bis(2-methoxyethylindenyl)lanthanum and yttrium tetrahydroborates[J]. Polyhedron,2000,19(16-17):1955-1959.
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