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学科主题: 金属有机化学
题名: Asymmetric glyoxylate-ene reaction catalyzed by C^2-symmetric chiral bis(oxazoline)-lanthanide complexes
其他题名: C^2-对称手性噁唑啉-稀土配合物催化的不对称 ene 反应
作者: Qian ZT(钱长涛) ; Wang LC(王龙成)
通讯作者: 钱长涛
刊名: Tetrahedron-Asymmetry
发表日期: 2000-01-01
卷: 11, 期:11, 页:2347-2357
收录类别: SCI
部门归属: 中国科学院上海有机化学研究所金属有机化学开放实验室
英文摘要: Effcient C^2-symmetric chiral bis(oxazoline)-lanthanide catalysts are developed for the glyoxylate-ene reaction to afford the α-hydroxy esters in 85% yield and up to 54% ee. An enhanced level of diastereoselectivity (81% de) was obtained in the reaction between menthyl glyoxylate and alkenes catalyzed by bis (oxazoline)-Ln(Otf)^3 complex.
语种: 英语
相关网址: 查看原文
内容类型: 期刊论文
URI标识: http://ir.sioc.ac.cn/handle/331003/15203
Appears in Collections:金属有机化学国家重点实验室_期刊论文

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Recommended Citation:
Qian ZT,Wang LC. Asymmetric glyoxylate-ene reaction catalyzed by C^2-symmetric chiral bis(oxazoline)-lanthanide complexes[J]. Tetrahedron-Asymmetry,2000,11(11):2347-2357.
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