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学科主题: 金属有机化学
题名: First application of amino-TADDOL derivatives in enantioselective addition of diethylzinc to aryl alkehydes: effct of substituents on the nitrogen atom
其他题名: 氨基酒石酸醇衍生物首次催化二乙基锌与芳醛的不对称加成反应
作者: Qian ZT(钱长涛) ; Gao FF(高飞峰) ; Sun J(孙杰)
通讯作者: 钱长涛
刊名: Tetrahedron-Asymmetry
发表日期: 2000-01-01
卷: 11, 期:8, 页:1733-1740
收录类别: SCI
部门归属: 中国科学院上海有机化学研究所金属有机化学开放实验室
英文摘要: Five amino-TADDOL derivatives have been used as catalysts for the enantioselective addition of diethylzinc to aromatic aldehydes. Moderate to good enantioselectivities were obtained (up to 88% ee). The substituents on the nitrogen atom play an important role in the stereochemistry, even reversing the enantioselectivity. The effects of Li salts of aminoalcohols on the reaction were explored.
语种: 英语
相关网址: 查看原文
内容类型: 期刊论文
URI标识: http://ir.sioc.ac.cn/handle/331003/15201
Appears in Collections:金属有机化学国家重点实验室_期刊论文

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Recommended Citation:
Qian ZT,Gao FF,Sun J. First application of amino-TADDOL derivatives in enantioselective addition of diethylzinc to aryl alkehydes: effct of substituents on the nitrogen atom[J]. Tetrahedron-Asymmetry,2000,11(8):1733-1740.
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