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[2+2] Cycloaddition reactions of imines with alkynyl selenides catalyzed by scandium triflate
Alternative Title钪三氟甲基磺酸盐催化的涯胺与硒炔之间的[2+]环成反应
Ma Y(马云); Qian ZT(钱长涛)
2000
Source PublicationTetrahedron Lett.
ISSN0040-4039
Volume41Issue:6Pages:945-947
AbstractIt was found that a new reaction of imines with alkynyl selenides proceeded smoothly in the presence of a catalytic amount of Sc(Otf)^3 affording α,β-unsaturated selenylimidates. These reactions are assumed to proceed by 1 [2+2] cycloaddition of the imines to the alkynyl selenides to form azetine intermediates, which are unstable and immediately fragment to the corresponding α,β-unsaturated selenylimidates.
Subject Area金属有机化学 ; 有机氟化学
Department中国科学院上海有机化学研究所金属有机化学开放实验室
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Indexed BySCI
Language英语
WOS IDWOS:000085305600038
Citation statistics
Cited Times:36[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://ir.sioc.ac.cn/handle/331003/15199
Collection金属有机化学国家重点实验室
Corresponding AuthorQian ZT(钱长涛)
Recommended Citation
GB/T 7714
Ma Y,Qian ZT. [2+2] Cycloaddition reactions of imines with alkynyl selenides catalyzed by scandium triflate[J]. Tetrahedron Lett.,2000,41(6):945-947.
APA 马云,&钱长涛.(2000).[2+2] Cycloaddition reactions of imines with alkynyl selenides catalyzed by scandium triflate.Tetrahedron Lett.,41(6),945-947.
MLA 马云,et al."[2+2] Cycloaddition reactions of imines with alkynyl selenides catalyzed by scandium triflate".Tetrahedron Lett. 41.6(2000):945-947.
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