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学科主题: 金属有机化学 ; 有机氟化学
题名: [2+2] Cycloaddition reactions of imines with alkynyl selenides catalyzed by scandium triflate
其他题名: 钪三氟甲基磺酸盐催化的涯胺与硒炔之间的[2+]环成反应
作者: Ma Y(马云) ; Qian ZT(钱长涛)
通讯作者: 钱长涛
刊名: Tetrahedron Lett.
发表日期: 2000
卷: 41, 期:6, 页:945-947
收录类别: SCI
部门归属: 中国科学院上海有机化学研究所金属有机化学开放实验室
英文摘要: It was found that a new reaction of imines with alkynyl selenides proceeded smoothly in the presence of a catalytic amount of Sc(Otf)^3 affording α,β-unsaturated selenylimidates. These reactions are assumed to proceed by 1 [2+2] cycloaddition of the imines to the alkynyl selenides to form azetine intermediates, which are unstable and immediately fragment to the corresponding α,β-unsaturated selenylimidates.
语种: 英语
相关网址: 查看原文
WOS记录号: WOS:000085305600038
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内容类型: 期刊论文
URI标识: http://ir.sioc.ac.cn/handle/331003/15199
Appears in Collections:金属有机化学国家重点实验室_期刊论文

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Recommended Citation:
Ma Y,Qian ZT. [2+2] Cycloaddition reactions of imines with alkynyl selenides catalyzed by scandium triflate[J]. Tetrahedron Lett.,2000,41(6):945-947.
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