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学科主题: 金属有机化学 ; 有机氟化学
题名: Addition of silyl ketene acetals to nitrones catalyzed by lanthanide triflates
其他题名: 稀土三氟甲基磺酸盐催化的甲硅基乙烯酮缩乙二醇对硝酮的加成反应
作者: Qian ZT(钱长涛) ; Wang LC(王龙成)
通讯作者: 钱长涛
刊名: Tetrahedron
发表日期: 2000
卷: 56, 期:37, 页:7193-7197
收录类别: SCI
部门归属: 中国科学院上海有机化学研究所金属有机化学开放实验室
英文摘要: α--Aryl-N-phenyl nitrones reacted with silyl ketene acetals mediated by lanthanum trifloromethanesulfonate (triflate) to afford the addition product in excellent yield under mild conditions. Α-Aryl-N-tert-butyl nitrone reacted with ethyl trimethylsilylacetate to yield the unexpected α,β-unsaturated ester in a 100% E-form. A possible mechanism for the process is discussed.
语种: 英语
相关网址: 查看原文
WOS记录号: WOS:000089149200011
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内容类型: 期刊论文
URI标识: http://ir.sioc.ac.cn/handle/331003/15195
Appears in Collections:金属有机化学国家重点实验室_期刊论文

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Recommended Citation:
Qian ZT,Wang LC. Addition of silyl ketene acetals to nitrones catalyzed by lanthanide triflates[J]. Tetrahedron,2000,56(37):7193-7197.
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