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学科主题: 金属有机化学
题名: Palladium(II)-Catalyzed Synthesis of Functionalized Indenes from o-Alkynylbenzylidene Ketones
其他题名: 两价钯催化下从邻炔基苯亚甲基酮合成官能团化茚
作者: Zhou F(周峰) ; Han XL(韩秀玲) ; Lu XY(陆熙炎)
通讯作者: 陆熙炎
刊名: J. Org. Chem.
发表日期: 2011
卷: 76, 期:5, 页:1491-1494
收录类别: SCI
部门归属: 中科院上海有机化学研究所
英文摘要: An efficient method for the synthesis of functionalized indenes from o-alkynylbenzylidene ketones under palladium(II) catalysis was developed. The reaction is initiated by trans-nucleopalladation of alkynes, followed by conjugate addition and quenched by protonolysis of the carbon palladium bond. With acetate and halide ions as nucleophiles, 3-acetoxy- and 3-halogen-substituted indenes could be obtained in high yields.
语种: 英语
相关网址: 查看原文
WOS记录号: WOS:000287636200038
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内容类型: 期刊论文
URI标识: http://ir.sioc.ac.cn/handle/331003/14902
Appears in Collections:金属有机化学国家重点实验室_期刊论文

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Recommended Citation:
Zhou F,Han XL,Lu XY. Palladium(II)-Catalyzed Synthesis of Functionalized Indenes from o-Alkynylbenzylidene Ketones[J]. J. Org. Chem.,2011,76(5):1491-1494.
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