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学科主题: 金属有机化学
题名: Cationic Pd(II)-catalyzed enantioselective cyclization of aroylmethyl 2-alkynoates initiated by carbopalladation of alkynes with arylboronic acids
其他题名: Cationic Pd(II)-catalyzed enantioselective cyclization of aroylmethyl 2-alkynoates initiated by carbopalladation of alkynes with arylboronic acids
作者: Song J(宋娟) ; Shen Q(沈琪) ; Xu F(徐凡) ; Lu XY(陆熙炎)
通讯作者: 沈琪 ; 陆熙炎
刊名: Org. Lett.
发表日期: 2007
卷: 9, 期:15, 页:2947-2950
收录类别: SCI
部门归属: 上海有机所; 苏州大学
英文摘要: A cationic palladium(II)-catalyzed enantioselective intramolecular addition of vinylpalladium species to ketones initiated by the carbopalladation of alkynoates under mild conditions without a Pd(II)/Pd(0) redox system was developed with high yield and enantioselectivity. This cascade reaction provides an efficient method for the construction of optically active hydroxylactones.
语种: 英语
相关网址: 查看原文
WOS记录号: WOS:000247966400049
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内容类型: 期刊论文
URI标识: http://ir.sioc.ac.cn/handle/331003/14862
Appears in Collections:金属有机化学国家重点实验室_期刊论文

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Recommended Citation:
Song J,Shen Q,Xu F,et al. Cationic Pd(II)-catalyzed enantioselective cyclization of aroylmethyl 2-alkynoates initiated by carbopalladation of alkynes with arylboronic acids[J]. Org. Lett.,2007,9(15):2947-2950.
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