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学科主题: 金属有机化学
题名: Cycloisomerization of 1,6-enynes using acetate as a nucleophile under palladium(II) catalysis
其他题名: 钯(II)催化的以乙酸基为亲核试剂的1,6-烯炔的环异构化
作者: Zhang QH(张庆海) ; Xu Y(许蔚) ; Lu XY(陆熙炎)
通讯作者: 陆熙炎
刊名: J. Org. Chem.
发表日期: 2005
卷: 70, 期:4, 页:1505-1507
收录类别: SCI
部门归属: 上海有机化学研究所
英文摘要: An efficient method for the synthesis of five-membered carbo- and heterocyclic compounds, including fused rings, was reported using acetate as a nucleophile in the cyclization of 1,6-enynes under palladium(II) catalysis. The reaction is initiated by trans-acetoxypalladation of the alkynes and quenched by either trans- or cis-deacetoxypalladation in the presence of 2,2'-bipyridine as the ligand. An example of the catalytic asymmetric cyclization is presented with moderate enantioselectivity using chiral bisoxazoline ligand.
语种: 英语
相关网址: 查看原文
WOS记录号: WOS:000227075600056
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内容类型: 期刊论文
URI标识: http://ir.sioc.ac.cn/handle/331003/14834
Appears in Collections:金属有机化学国家重点实验室_期刊论文

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Recommended Citation:
Zhang QH,Xu Y,Lu XY. Cycloisomerization of 1,6-enynes using acetate as a nucleophile under palladium(II) catalysis[J]. J. Org. Chem.,2005,70(4):1505-1507.
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