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学科主题: 金属有机化学
题名: A novel highly regio- and diastereoselective haloamination of alkenes catalyzed by divalent palladium
其他题名: 一个新的二价钯催化的高区域性和非对映选择性的烯烃卤胺化反应
作者: Lei AW(雷爱文) ; Lu XY(陆熙炎) ; Liu GS(刘国生)
通讯作者: 陆熙炎
刊名: Tetrahedron Lett.
发表日期: 2004
卷: 45, 期:8, 页:1785-1788
收录类别: SCI
部门归属: 中国科学院上海有机化学研究所金属有机化学实验室
英文摘要: From the readily available allylic alcohols or allylic amines, a novel Pd(II)-CuCl2 -catalyzed haloamination reaction of alkenes with high chemo-, regio-, and diastereo-selectivity was developed. The reaction proceeds through trans-aminopalladation of alkenes, followed by oxidative cleavage of the carbon-palladium bond with retention of configuration. (C) 2003 Elsevier Ltd. All rights reserved.
语种: 英语
相关网址: 查看原文
WOS记录号: WOS:000188890500047
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内容类型: 期刊论文
URI标识: http://ir.sioc.ac.cn/handle/331003/14824
Appears in Collections:金属有机化学国家重点实验室_期刊论文

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Recommended Citation:
Lei AW,Lu XY,Liu GS. A novel highly regio- and diastereoselective haloamination of alkenes catalyzed by divalent palladium[J]. Tetrahedron Lett.,2004,45(8):1785-1788.
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