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学科主题: 金属有机化学
题名: Palladium(II)-catalyzed three-component coupling reaction initiated by acetoxypalladation of alkynes: An efficient route to γ,δ-Unsaturated carbonyls
其他题名: 由炔烃乙酰氧钯化启动的钯(II)催化的三组分偶合反应: 一个有效的合成g,d-不饱和羰基化合物的方法
作者: Zhao LG(赵立刚) ; Lu XY(陆熙炎)
通讯作者: 陆熙炎
刊名: Org. Lett.
发表日期: 2002-01-01
卷: 4, 期:22, 页:3903-3906
收录类别: SCI
部门归属: 中国科学院上海有机化学研究所金属有机化学开放实验室
英文摘要: A divalent palladium-catalyzed coupling reaction of electron-deficient alkynes and acrolein or NVK (methyl vinyl ketone) was developed. The reaction provides an efficient method to synthesize γ,δ-unsaturated carbonyls. A mechanism involving acetoxypalladation of alkyne, followed by insertion of alkene and protonolysis of the C-Pd bond, is proposed. The protonolysis of the carbon-palladium bond with the assistance of bidentate nitrogen containing ligands is the key step in this tandem reaction.
语种: 英语
相关网址: 查看原文
内容类型: 期刊论文
URI标识: http://ir.sioc.ac.cn/handle/331003/14806
Appears in Collections:金属有机化学国家重点实验室_期刊论文

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Recommended Citation:
Zhao LG,Lu XY. Palladium(II)-catalyzed three-component coupling reaction initiated by acetoxypalladation of alkynes: An efficient route to γ,δ-Unsaturated carbonyls[J]. Org. Lett.,2002,4(22):3903-3906.
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