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学科主题: 金属有机化学
题名: Palladium(II)-catalyzed coupling reactions of alkynes and allylic compounds initiated by intramolecular carbopalladstion of alkynes
其他题名: 钯(II)催化下分子内炔烃的碳钯化和烯丙基化合物的偶合反应
作者: Liu GS(刘国胜) ; Lu XY(陆熙炎)
通讯作者: 陆熙炎
刊名: Tetrahedron Lett.
发表日期: 2002-01-01
卷: 43, 期:38, 页:6791-6794
收录类别: SCI
部门归属: 中国科学院上海有机化学研究所金属有机化学开放实验室
英文摘要: Under divalent palladium catalysis, a highly regio-and stereoselective coupling reaction of alkynes with allyl halides initiated by cyclocarbopalladation of alkynes proceeded smoothly in the presence of excess halide ions. The reaction involves intramolecular carbopalladation, allylic compound insertion into the vinylic-Pd bond and quenching the C-Pd bond by β-heteroatom elimination in one step without using oxidants.
语种: 英语
相关网址: 查看原文
内容类型: 期刊论文
URI标识: http://ir.sioc.ac.cn/handle/331003/14804
Appears in Collections:金属有机化学国家重点实验室_期刊论文

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Recommended Citation:
Liu GS,Lu XY. Palladium(II)-catalyzed coupling reactions of alkynes and allylic compounds initiated by intramolecular carbopalladstion of alkynes[J]. Tetrahedron Lett.,2002,43(38):6791-6794.
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