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学科主题: 金属有机化学
题名: Palladium(II)-catalyzed highly regio-and diastereoselective cyclization of difunctional allylic N-tosylcarbamates. A convenient synthesis of optically active 4-vinyl-2-oxazolidinones and total synthesis of 1,4-dideoxy-1,4-imino-L-xylitol
其他题名: 钯(II)催化的高区域和立体选择性的烯丙基双N-对甲苯磺基氨基甲酸酯的环化反应. 光学活性1,4-二脱氧-1,4-亚胺基-L-木糖醇的简单合成
作者: Lei AW(雷爱文) ; Liu GS(刘国胜) ; Lu XY(陆熙炎)
通讯作者: 陆熙炎
刊名: J. Org. Chem.
发表日期: 2002-01-01
卷: 67, 期:3, 页:974-980
收录类别: SCI
部门归属: 中国科学院上海有机化学研究所金属有机化学开放实验室
英文摘要: A Pd(II)-catalyzed cyclization of difunctional allylic N-tosyl carbamates in the presence of halide ions was developed with gigh regio-and diastereoselectivity. The reaction involves aminopalladation of alkene and β-heteroatom elimination to regenerate Pd(II) species. When the readily available homochiralalcohols alcohols were used as substrates, highly optically active 4-vinyl-2-oxazolidinones were easily obtained. The utility of this method was exemplified by the convenient synthesis of 1,4-dideoxy-1,4-imino-L-xylitol.
语种: 英语
相关网址: 查看原文
内容类型: 期刊论文
URI标识: http://ir.sioc.ac.cn/handle/331003/14800
Appears in Collections:金属有机化学国家重点实验室_期刊论文

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Recommended Citation:
Lei AW,Liu GS,Lu XY. Palladium(II)-catalyzed highly regio-and diastereoselective cyclization of difunctional allylic N-tosylcarbamates. A convenient synthesis of optically active 4-vinyl-2-oxazolidinones and total synthesis of 1,4-dideoxy-1,4-imino-L-xylitol[J]. J. Org. Chem.,2002,67(3):974-980.
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