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学科主题: 金属有机化学
题名: Palladium(II)-catalyzed synthesis of α-alkylidene-γ-butyrolactams from N-allylic 2-alkynamides. Total synthesis of (±)-Isocynodine and (±)-isocynometrine
其他题名: 二价钯催化的从N-烯丙基2-炔酰胺合成α-亚烷基-γ-丁内酯。 (±)-Isocynodine和(±)-Isocynometrine 的全合成
作者: Xie X(谢煦) ; Lu XY(陆熙炎) ; Xu W(徐伟)
通讯作者: 陆熙炎
刊名: J. Org. Chem.
发表日期: 2001-01-01
卷: 66, 期:20, 页:6545-6550
收录类别: SCI
部门归属: 中国科学院上海有机化学研究所金属有机化学开放实验室
英文摘要: An efficient method for preparing α-alkylidene-γ-butyrolactams via the Pd(II)-catalyzed cyclization of acyclic N-allylic 2-alkynamides via halopalladation, intramolecular olefin insertion, and β-heteroatom elimination was developed. The reaction is less influenced by the leaving group and the concentration of the halide ions in comparison with the cyclization of acyclic alkynoates. The total syntheses of ±-isocynodine and ±-isocynometrine were realized using this method
语种: 英语
相关网址: 查看原文
内容类型: 期刊论文
URI标识: http://ir.sioc.ac.cn/handle/331003/14790
Appears in Collections:金属有机化学国家重点实验室_期刊论文

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Recommended Citation:
Xie X,Lu XY,Xu W. Palladium(II)-catalyzed synthesis of α-alkylidene-γ-butyrolactams from N-allylic 2-alkynamides. Total synthesis of (±)-Isocynodine and (±)-isocynometrine[J]. J. Org. Chem.,2001,66(20):6545-6550.
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