中国科学院上海有机化学研究所机构知识库
Advanced  
SIOC OpenIR  > 金属有机化学国家重点实验室  > 期刊论文
学科主题: 金属有机化学
题名: Role of halide ions in divalent palladium-mediated reactions: competition between β-heteroatom elimination and β-hydride elimination of a carbon-palladium bond
其他题名: 卤离子在二价钯启动的反应的作用: 碳-钯键的β-杂原子消除和β-氢消除的竞争
作者: Zhang ZG(张兆国) ; Lu XY(陆熙炎) ; Xu ZR(徐振荣) ; Zhang QH(张庆海) ; Han XL(韩秀玲)
通讯作者: 陆熙炎
刊名: Organometallics
发表日期: 2001-01-01
卷: 20, 期:17, 页:3724-3728
收录类别: SCI
部门归属: 中国科学院上海有机化学研究所金属有机化学开放实验室
英文摘要: The integral role of halide ions as a ligand in the reactions of stoichiometric arylpalladium reagents and Pd(II)-catalyzed reaction of phenylmercuric acetate with various allylic compounds were studied. The halide ion was found to inhibit β-H elimination and promote β-heteroatom elimination in acidic media. In this reaction, a C-Pd intermediate with a β-heteroatom (including halogen, acetoxy, alkoxy, and hydroxyl groups) gives only β-heteroatom elimination product in the presence of halide ions, while β-H elimination is effectively blocked.
语种: 英语
相关网址: 查看原文
内容类型: 期刊论文
URI标识: http://ir.sioc.ac.cn/handle/331003/14788
Appears in Collections:金属有机化学国家重点实验室_期刊论文

Files in This Item: Download All
File Name/ File Size Content Type Version Access License
2001156.pdf(503KB)----开放获取--View Download

Recommended Citation:
Zhang ZG,Lu XY,Xu ZR,et al. Role of halide ions in divalent palladium-mediated reactions: competition between β-heteroatom elimination and β-hydride elimination of a carbon-palladium bond[J]. Organometallics,2001,20(17):3724-3728.
Service
Recommend this item
Sava as my favorate item
Show this item's statistics
Export Endnote File
Google Scholar
Similar articles in Google Scholar
[张兆国]'s Articles
[陆熙炎]'s Articles
[徐振荣]'s Articles
CSDL cross search
Similar articles in CSDL Cross Search
[张兆国]‘s Articles
[陆熙炎]‘s Articles
[徐振荣]‘s Articles
Related Copyright Policies
Null
Social Bookmarking
Add to CiteULike Add to Connotea Add to Del.icio.us Add to Digg Add to Reddit
文件名: 2001156.pdf
格式: Adobe PDF
此文件暂不支持浏览
所有评论 (0)
暂无评论
 
评注功能仅针对注册用户开放,请您登录
您对该条目有什么异议,请填写以下表单,管理员会尽快联系您。
内 容:
Email:  *
单位:
验证码:   刷新
您在IR的使用过程中有什么好的想法或者建议可以反馈给我们。
标 题:
 *
内 容:
Email:  *
验证码:   刷新

Items in IR are protected by copyright, with all rights reserved, unless otherwise indicated.

 

 

Valid XHTML 1.0!
Powered by CSpace