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学科主题: 金属有机化学
题名: Effect of ligands on the divalent palladiumcatalyzed carbon-carbon coupling reactions. Highly enantioselective synthesis of optically active γ-butyrolactones.
其他题名: 二价钯催化的碳-碳偶联反应中配体的影响。 光学活性γ-丁内酯的高对映选择性合成
作者: Lu XY(陆熙炎) ; Zhang QH(张庆海)
通讯作者: 陆熙炎
刊名: Pure Appl. Chem.
发表日期: 2001-01-01
卷: 73, 期:2, 页:247-250
收录类别: SCI
部门归属: 中国科学院上海有机化学研究所金属有机化学开放实验室
英文摘要: In the palladium(II)-catalyzed enyne coupling reactions, the nitrogen-containing ligand plays the same role as the halide ion to inhibit the β-hydride elimination. Employing the pymox or bisoxazoline as ligands, the catalytic asymmetric cyclization of (Z)-4'-acetoxy-2'-butenyl 2-alkynoates initiated by acetoxypalladation was established with high effciency (up to 92% ee) to afford the optically active γ-butyrolactones.
语种: 英语
相关网址: 查看原文
内容类型: 期刊论文
URI标识: http://ir.sioc.ac.cn/handle/331003/14786
Appears in Collections:金属有机化学国家重点实验室_期刊论文

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Recommended Citation:
Lu XY,Zhang QH. Effect of ligands on the divalent palladiumcatalyzed carbon-carbon coupling reactions. Highly enantioselective synthesis of optically active γ-butyrolactones.[J]. Pure Appl. Chem.,2001,73(2):247-250.
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