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学科主题: 金属有机化学
题名: Palladium(II)-catalyzed tandem reaction of intramolecular aminopalladation of allenyl N-tosylcarbamates and conjugate addition
其他题名: 二价钯催化下N-对甲苯磺酰基胺基甲算联烯酯分子内胺钯化和共轭加成的串联反应
作者: Liu GS(刘国生) ; Lu XY(陆熙炎)
通讯作者: 陆熙炎
刊名: Org. Lett.
发表日期: 2001
卷: 3, 期:24, 页:3879-3882
收录类别: SCI
部门归属: 中国科学院上海有机化学研究所金属有机化学开放实验室
英文摘要: A divalent palladium-catalyzed tandem cyclization-coupling reaction of allenyl N-tosylcarbamates and acrolein was developed. The reaction gave aldehyde-functionalized 2-oxazolidinones in one step with high regioselectivity. A mechanism involving intramolecular aminopalladation of allene, followed by insertion of alkene and C-Pd bond protonlysis, is proposed.
语种: 英语
相关网址: 查看原文
WOS记录号: WOS:000172418200016
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内容类型: 期刊论文
URI标识: http://ir.sioc.ac.cn/handle/331003/14782
Appears in Collections:金属有机化学国家重点实验室_期刊论文

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Recommended Citation:
Liu GS,Lu XY. Palladium(II)-catalyzed tandem reaction of intramolecular aminopalladation of allenyl N-tosylcarbamates and conjugate addition[J]. Org. Lett.,2001,3(24):3879-3882.
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