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Reactions of electron-deficient alkynes and allenes under phosphine catalysis
Alternative Title叔膦催化下贫电子炔烃的反应
Lu XY(陆熙炎); Zhang CM(张春明); Xu ZR(徐振荣)
2001
Source PublicationAccounts Chem. Res.
ISSN0001-4842
Volume34Issue:7Pages:535-544
AbstractThe development of some new synthetic reactions derived from nucleophilic addition of phosphines to electron-deficient carboncarbon triple bonds is described. These reactions show that the phosphine plays the role of a nucleophile as well as an excellent leaving group. The central problem is to generate a 1,3-dipole from alkynoates or allenoates (2,3-butadienoates) by interaction with various phosphines. This study illuminates the unusual phenomena and shows how this understanding allows control of the reaction.
Subject Area元素有机化学
Department中国科学院上海有机化学研究所金属有机化学开放实验室
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Indexed BySCI
Language英语
WOS IDWOS:000170173900002
Citation statistics
Cited Times:818[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://ir.sioc.ac.cn/handle/331003/14780
Collection金属有机化学国家重点实验室
Corresponding AuthorLu XY(陆熙炎)
Recommended Citation
GB/T 7714
Lu XY,Zhang CM,Xu ZR. Reactions of electron-deficient alkynes and allenes under phosphine catalysis[J]. Accounts Chem. Res.,2001,34(7):535-544.
APA 陆熙炎,张春明,&徐振荣.(2001).Reactions of electron-deficient alkynes and allenes under phosphine catalysis.Accounts Chem. Res.,34(7),535-544.
MLA 陆熙炎,et al."Reactions of electron-deficient alkynes and allenes under phosphine catalysis".Accounts Chem. Res. 34.7(2001):535-544.
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