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学科主题: 金属有机化学
题名: Role of halide ions in palladium(II)catalyzed nucelophile-alkyne-α,β-Unsaturated carbonyl coupling reactions
其他题名: 卤离子在钯(II)催化亲核试剂-炔烃-α,β不饱和羰基化合物偶联反应中的作用
作者: Lu XY(陆熙炎) ; Wang Z(王忠)
通讯作者: 陆熙炎
刊名: Polyhedron
发表日期: 2000-01-01
卷: 19, 期:5, 页:577-579
收录类别: SCI
部门归属: 中国科学院上海有机化学研究所金属有机化学开放实验室
英文摘要: The integral role of halide ions as a ligand in divalent palladium catalyzed nucleophile alkyne-α,β-unsaturated carbonyl coupling reactions as well as in the stoichiometric reaction of arylpalladium reagents with acrolein was studied Excess of halide ions can effectively inhibit the β-hydride elimination of a 2-oxoalkyl)palladium intermediate, giving preferentially the protonolysis product in acidic media.
语种: 英语
相关网址: 查看原文
内容类型: 期刊论文
URI标识: http://ir.sioc.ac.cn/handle/331003/14770
Appears in Collections:金属有机化学国家重点实验室_期刊论文

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Recommended Citation:
Lu XY,Wang Z. Role of halide ions in palladium(II)catalyzed nucelophile-alkyne-α,β-Unsaturated carbonyl coupling reactions[J]. Polyhedron,2000,19(5):577-579.
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