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学科主题: 金属有机化学
题名: Effect of halide ligands on the reactivity of carbon-palladium bonds: Implications for desigining catalytic reactions
其他题名: 卤离子配体对碳-钯键反应性的影响:有关催化反应的设计
作者: Wang Z(王忠) ; Zhang ZG(张兆国) ; Lu XY(陆熙炎)
通讯作者: 陆熙炎
刊名: Organometallics
发表日期: 2000-01-01
卷: 19, 期:5, 页:775-780
收录类别: SCI
部门归属: 中国科学院上海有机化学研究所金属有机化学开放实验室
英文摘要: The integral role of halide ions as a ligand in divalent palladium-catalyzed nucleophilealkyne-α,β-unsaturated carbonyl coupling reaction as well as in the stoichiometric reaction of arylpalladium reagents with acrolein was studied. Excess of halide ions can effectively inhibit theβ-hydride elimination of a (2-oxoalkyl)palladium intermediate, giving preferentially the protonolysis product in acidic media. This result may have further implications for the design and development of divalent palladium-catalyzed reactions
语种: 英语
相关网址: 查看原文
内容类型: 期刊论文
URI标识: http://ir.sioc.ac.cn/handle/331003/14768
Appears in Collections:金属有机化学国家重点实验室_期刊论文

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Recommended Citation:
Wang Z,Zhang ZG,Lu XY. Effect of halide ligands on the reactivity of carbon-palladium bonds: Implications for desigining catalytic reactions[J]. Organometallics,2000,19(5):775-780.
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