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学科主题: 有机氟化学
题名: Iodine-promoted imino-Diels-Alder reaction of fluorinated imine with enol ether: synthesis of 2-perfluorophenyl tetrahydroquinoline derivatives
其他题名: 碘促进的亚氨基-Diels-Alder反应的氟化烯醚亚胺: 2-perfluorophenyl四氢衍生物的合成
作者: Jin GF(金桂芳) ; Zhao JW(赵经纬) ; Han JW(韩建伟) ; Zhu SZ(朱仕正) ; Zhang JM(章建民)
通讯作者: 朱仕正
刊名: Tetrahedron
发表日期: 2010
卷: 66, 期:4, 页:913-917
收录类别: SCI
部门归属: 中国科学院上海有机化学研究所; 上海大学
英文摘要: Iodine was used to catalyze the hetero-Diels-Aider reaction of pentafluorobenzylidineaniline (C6F5CH=NAr 1) with enol ethers to afford the corresponding tetrahydroquinolines derivatives as a mixture of cis/trans stereoisomers in moderate yields. These products could also be prepared by onepot, three-component reaction of pentafluorophenylaldehyde, anilines, and enol ethers under the same reaction condition. Mild and neutral reaction conditions, facile experimental procedure, and low price of iodine should make this method attractive for practical synthesis of many fluorinated tetrahydroquinoline derivatives. (C) 2009 Elsevier Ltd. All rights reserved.
语种: 英语
相关网址: 查看原文
WOS记录号: WOS:000274822000011
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内容类型: 期刊论文
URI标识: http://ir.sioc.ac.cn/handle/331003/14496
Appears in Collections:中科院有机氟化学重点实验室_期刊论文

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Recommended Citation:
Jin GF,Zhao JW,Han JW,et al. Iodine-promoted imino-Diels-Alder reaction of fluorinated imine with enol ether: synthesis of 2-perfluorophenyl tetrahydroquinoline derivatives[J]. Tetrahedron,2010,66(4):913-917.
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