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学科主题: 金属有机化学
题名: Synthesis and Photophysics of Novel Soluble Polymeric Zn Metal Complex Based on Bis(8-hydroxyquinoline) Groups with Benzene Unit
其他题名: 合成新型水溶性高分子双8-羟基喹啉苯单元组的锌金属配合物和光物理的研究
作者: Huo YP(霍延平) ; Zhu SZ(朱仕正)
通讯作者: 霍延平 ; 朱仕正
刊名: Chin. J. Chem.
发表日期: 2010
卷: 28, 期:8, 页:1389-1394
收录类别: SCI
部门归属: 广东工业大学; 中国科学院上海有机化学研究所
英文摘要: A novel ligand: 2,2'-(1,3-phenylenedivinylene)bis-8-hydroxyquinoline (m-B8QPH) (4) and the corresponding polymeric metal complex Zn(m-B8QPH) (5) were designed and synthesized in a convenient way. The luminescence properties of the compounds Zn(m-B8QPH) (5) and Zn(p-B8QPH) (9) were investigated by UV-vis and fluorescence spectra in DMF at room temperature. The experimental results showed that the polymeric complexes 5 and 9 emitted yellow luminescence at 578 and 554 nm in DMF solution. The polymeric complex 5 has demonstrated good solubility in common organic solvents and good thermal stability with high T-g: 261 degrees C. Furthermore, the molecular interactions of 5 with fullerene (C-60) and fulleropyrrolidine containing 3,5-bis(trifluoromethyl)benzene (11) were also investigated, which indicated the metal dye 5 can be used as new fluorescent probe.
语种: 英语
相关网址: 查看原文
WOS记录号: WOS:000281546600013
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内容类型: 期刊论文
URI标识: http://ir.sioc.ac.cn/handle/331003/14484
Appears in Collections:中科院有机氟化学重点实验室_期刊论文

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Recommended Citation:
Huo YP,Zhu SZ. Synthesis and Photophysics of Novel Soluble Polymeric Zn Metal Complex Based on Bis(8-hydroxyquinoline) Groups with Benzene Unit[J]. Chin. J. Chem.,2010,28(8):1389-1394.
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